Ingredient
4-METHYLBENZYLIDENE CAMPHOR
Name / description
4-Methylbenzylidene Camphor; 3-(4-Methylbenzylidene)-2-bornanone; Enzacamene
Function(s) of this ingredient in cosmetic products
LIGHT STABILIZER
Protecting the cosmetic product from deterioration effects of light
UV ABSORBER
Protects the cosmetic product from damage caused by UV light
UV FILTER
Protects skin or hair from harmful UV radiation
Origin
synthetic/plant
Occurrence in cosmetics
As a UV filter in sunscreens and other cosmetics with UV protection (care products, decorative cosmetics)
Background information on use in cosmetics
4-Methylbenzylidene Camphor (abbreviation: 4-MBC) is a soluble organic UV-B filter. It absorbs UV-B radiation from approximately 280 to 320 nm. The maximum concentration of 4-MBC is 4 %. UV filters minimise the undesired effects of UV radiation on the skin and are, therefore, an important component of sunscreens. By protecting the skin against the dangerous sun radiation, they contribute towards preventing premature light-caused skin ageing and skin cancer. In this connection a distinction is made between soluble organic UV filters and those based on mineral and / or organic pigments. Whereas soluble organic UV filters absorb the UV radiation, transform it into heat and form an invisible protection shield in the upper skin layer, UV filters on the basis of pigments reflect, scatter and absorb the sun radiation already on the skin surface. Organic UV filters absorb the energy of the ultraviolet part of the light in the range from approximately 280 to 400 nm. In this connection the energy of the absorbed photon must correspond to the energy which is necessary to elevate the electron in the molecule of the filter substance from a low to a higher orbit. When the electron falls back to its original orbit, the absorbed energy is either given off as heat or as radiation of a longer wavelength and hence rendered harmless. The organic UV filters are distinguished, amongst others, by the position of the absorption area, the photostability, the solubility and the penetration capacity. Depending on the wave area of the ultraviolet radiation which is absorbed by the UV filter, a distinction is made between UV-A, UV-B and broadband filters.
Information on safe use
In accordance with the EU Cosmetics Regulation [Regulation (EC) No. 1223/2009], which applies to the entire EU market, UV filters are defined as substances which are exclusively or mainly intended to protect the skin against certain UV radiation by absorbing, reflecting or scattering UV radiation. Annex VI of the Regulation defines the substances which may be used in cosmetic products as UV filters. In this so-called positive list of the UV filters maximum concentrations are prescribed for the use of these substances in cosmetic products and, if necessary, additional conditions for use are defined. Prior to their approval in Annex VI, UV filters are examined selectively for their toxicological safety and subjected to comprehensive tests. The manufacturers must prove the health safety in extensive scientific studies. Moreover, the approved filters are re-assessed, if necessary on the basis of new scientific findings and in the event of possible conspicuous findings in market observation and the list is updated accordingly.
Why are we talking about it?
4-Methylbenzylidene camphor (4-MBC) is suspected of being an endocrine disruptor. It is also suspected of polluting surface waters and of burdening aquatic organisms. The facts: 4-MBC has been evaluated as safe for use by (European) expert committees, but this evaluation has been challenged. In vitro data show effects on hormonal balance of estrogens and thyroid hormones. In vivo results are contradictory and further data are now still needed to clear the doubt. 4-MBC is one of the substances that have recently been re-evaluated by European experts with regard to a potential endocrine activity. Available results from in vivo experiments are inconclusive and further data are required in order to dispel all doubts. Current scientific knowledge supports the conclusion, that 4-MBC has the potential to interact with the endocrine system (affecting thyroid hormone and estrogen balance), resulting in adverse effects on living organisms at sufficiently high exposure levels. Key points to take away: With regard to endocrine effects, 4-MBC has been re-evaluated by the responsible scientific committee (SCCS) in 2022. Further use restrictions in cosmetic products have to be expected. With regard to environmental effects, 4-MBC is not easily biodegradable but does not persist in aquatic sediments, nor does it accumulate in aquatic organisms.
Further information
For the clarification of a suspicion of a contact allergy this substance can be routinely tested in the epicutaneous test at the dermatologist.
Belongs to the following substance groups
Regulating cosmetics
Cosmetics Ingredients are subject to regulation. Please note, different regulations may apply to cosmetic ingredients outside the EU.